NFM
Reactive Extrusion
NFM/Welding Engineers
has been building equipment for the finishing and
primary manufacture of emulsion, bulk, and solution
polymers ever since polymer manufacturers began using
twin screw devices for such purposes. Over time,
we have developed the technology to handle the large
amounts of solvent, water, or vapor that comes out
of the reactor with the polymer. We are the only
equipment manufacturer with the technology to finish
polymers commercially from emulsion, solution or
slurry in a single machine.
It was a natural extension of our expertise in handling
reactor products to perform the reactions themselves
in our extruders. For reactions to proceed to completion
in a controlled manner requires certain residence
time, heat transfer, and mass transfer characteristics.
NFM/Welding Engineers' extruders offer optimum conditions
in all three areas and our technical team can provide
ready solutions to limitations in reactive extrusion
process development.
The Advantages of an NFM/WE
Twin Screw Extruder
- Excellent
Heat Transfer Characteristics:
In conventional polymer processing,
a thermal gradient is something that has to be mixed out of the
polymer prior to extrusion. In reactive processing, thermal gradients
at any point in the extruder can give a variable rate reaction
or even promote the wrong reaction. Our counter-rotating, non-intermeshing
twin screw design provides excellent distributive mixing along
the entire witted length of the screws. The mixing is the result
of a flow pattern that provides multiple reorientations of the
melt. This pattern provides a low shear continuous homogenization
of the melt that effectively minimizes the magnitude of thermal
gradients.
In high viscosity fluids, the temperature of the fluid rises as
shear is applied to the fluid.
Removing the heat through conductive cooling may be ineffective
and will introduce thermal gradients in the polymer. To overcome
this problem, NFM/Welding Engineers applies direct inert fluid
contact technology. This technology was developed for our proprietary
emulsion finishing process in order to provide extensive cooling
capability. This technique avoids thermal gradients that accompany
any conductive cooling mechanism. Inert fluid rates in each stage
of the process can be as high as five times the polymer throughput
rate without reducing polymer throughput rate. Precise temperature
control is accomplished by regulating the stage pressure if the
inert fluid is boiling and by regulating the flow rate and temperature
of the inert fluid if it is not boiling.
- Excellent
Mass Transfer Characteristics:
Mass transfer in highly viscous fluids
is often rate-limiting in a reaction. NFM/Welding Engineers has
the experience to establish rapid intimate contact of the reactants,
regardless of whether the mass transfer is between a melt and a
liquid, a melt and a vapor, two melt streams, or a crumb and a
liquid or vapor. Our devolatilization technology can be readily
applied to polycondensation reactions or any melt vapor mass transfer
operation. Our mixing processing technology promotes contact between
co-continuous insoluble phases. The continuous reorientation mechanism
provides excellent distributive mixing of multiple melt phases.
- Excellent
Residence Time Characteristics:
Insufficient residence time is a common
cause for failure of reactive extrusion process development. A
residence time limitation will make the throughput capacity insufficient
to justify commercialization. Our non-intermeshing twin screw design
allows us to operate at higher throughput or longer residence time
than competitive designs.
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SUCCESSFUL REACTIVE EXTRUSION APPLICATIONS
- Grafting Reactions
- Acrylic Acid, Methacrylic
Acid, Maleic Anhydride Grafting to Polyolefins,
EP Rubber Vinylsiloxane Grafting to SEBS
Block Copolymer
- Dynamic Vulcanization
- Polyethylene (silane
crosslinking)
- Imidization of Acrylics
- And Many Other Proprietary
Reactions
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NFM/WE
Machine Capabilities
Capabilities for larger
machines available upon request.
Specifications are subject to change without
notice. |
Contact
Us
- For more information on reaction
or any other processes made possible by an
NFM/Welding Engineers' system, please contact
us. We would be glad to provide additional
data or technical support at any stage of your
project.
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